CORROSION PROTECTION OF STAINLESS STEEL TYPE 304 USING GRAPHENE COMPOSITES

Authors

  • Hesham Alhumade Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada N2L 3G
  • Hiba Nauman Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada N2L 3G1
  • Erij Elkamel Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada N2L 3G1
  • Aiping Yu Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada N2L 3G1
  • Ali Elkamel Department of Chemical Engineering, University of Waterloo, Waterloo, Ontario, Canada N2L 3G1

DOI:

https://doi.org/10.20319/mijst.2015.12.5772

Keywords:

Graphene, Corrosion, Adhesion, Coating, Electrochemical

Abstract

Polyetherimide-Graphene (PEI/G) composites were prepared using in situ polymerization approach and thermally cured under vacuum on Stainless Steel 304 (SS304) substrates in order to be evaluated as corrosion protection coatings. Several steps curing were performed to ensure complete imidization of PEI/G composites. Dispersion of the graphene fillers in the PEI matrices was captured using Scanning electron microscopy (SEM) and Transmission electron microscopy (TEM). The study examines PEI/G composites as corrosion protection coatings using electrochemical techniques such as Cyclic Voltammetry (CV) and Electrochemical Impedance Spectroscopy (EIS). Furthermore, the influences of the load of graphene on the electrochemical behavior as well as the interface adhesion of the PEI/G composites are illustrated. Adhesion tests were conducted and evaluated according to ASTM D3359 standard and the long term performances of the prepared PEI/G coatings were confirmed by conducting the adhesion tests after 30 days of exposure to the corrosive medium. The study revealed that PEI may slow down the corrosion process on SS304 substrates and this protection property of PEI can be excelled by the incorporation of graphene in the PEI matrix. 

References

ASTM International (2010). Standard Practice for Calculation of Corrosion Rates and Related Information from Electrochemical Measurements. West Conshohocken, PA. 10.1520/G0102-89R10

ASTM International (2009). Standard Test Methods for Measuring Adhesion by Tape Test. West Conshohocken, PA. 10.1520/D3359-09E02

Cecchetto, L., Delabouglise, D., Petit, J. P. (2007). On the mechanism of the anodic protection of aluminium alloy AA5182 by emeraldine base coatings: Evidences of a galvanic coupling. Electrochima Acta, 52(11), 3485-3492.

Chang, C. H., Huang, T. C., Peng, C. W., Yeh, T. C., Lu, H. I., Hung, W. I., Weng, C. J., Yang, T. I., Yeh, J. M. (2012). Novel anticorrosion coatings prepared from polyaniline/graphene composites. Carbon, 50(14), 5044-5051.

Chang, K. C., Hsu, C. H., Lu, H. I., Ji, W. F., Chang, C. H., Li, W. Y., Chuang, T. L., Yeh, J. M., Liu, W. R. (2014). Advanced anticorrosive coatings prepared from electroactive Polyimide/graphene nanocomposites with synergistic effects of redox catalytic capability and gas barrier properties. Express Polymer Letters, 8(4), 243-255.

Chang, K. C., Hsu, M. H., Lu, H. I., Lai, M. C., Liu, P. J., Hsu, C. H., Ji, W. F., Chuang, T. L., Wei, Y., Yeh, J. M., Liu, W. R. (2014). Room-temperature cured hydrophobic epoxy/graphene composites as corrosion inhibitor for cold-rolled steel. Carbon, 66, 144-153.

Crosby, A. J., Lee, J. (2007). Polymer nanocomposites: The “nano” effect on mechanical properties. Polym. Rev., 47(2), 217-229.

Guo, S. F., Zhang, H. J., Liu, Z., Chen, W., Xie, S. F. (2012). Corrosion resistances of amorphous and crystalline Zr-based alloys in simulated seawater. Electrochemistry Communications, 24, 39-42.

Kang, G., Kan, Q., Zhang, J., Sun, Y. (2005). Time-dependent ratchetting experiments of SS304 stainless steel. International Journal of Plasticity, 22(5), 858-894.

Moretti, G., Guidi, F., Grion, G. (2004). Tryptamine as a green iron corrosion inhibitor in 0.5 M deaerated sulphuric acid. Corrosion Science, 46(2), 387-403.

Ojha, O., Anjaneyulu, O., Ganguli, A. K. (2014). Graphene-based hybrid materials: synthetic approaches and properties. Current Science, 107 (3), 397-418.

Potts, J. R., Shankar, O., Du, L., Ruoff, R. S. (2012). Processing-morphology-property relationships and composite theory analysis of reduced graphene oxide/natural rubber nanocomposites. Macromolecules, 45(15), 6045-6055.

Prasai, D., Tuberquia, J. C., Harl, R. R., Jennings, G. K., Bolotin, K. I. (2012). Graphene: corrosion-inhibiting coating. ACS Nano, 6(2), 1102-1108.

Roy, D., Simon, G. P., Forsyth, M., Mardel, J. (2002). Towards a better understanding of the cathodic disbondment performance of polyethylene coatings on steel. Advances in Polymer Technology, 21(1), 44-58.

Shen, G. X., Chen, Y. C., Lin, C. J. (2005). Corrosion protection of 316 L stainless steel by a TiO2 nanoparticle coating prepared by sol-gel method. Thin Solid Films, 489(1-2), 130-136.

Singh, B. P., Jena, B. K., Bhattacharjee, S., Besra, L. (2013). Development of oxidation and corrosion resistance hydrophobic graphene oxide-polymer composite coating on copper. Surf. Coat. Tech, 232, 475-481.

The International Nickel Company Inc. (1963). Corrosion Resistance of the Austenitic chromium-nickel Stainless steels in chemical environments. New York.

Xu, Z., Buehler, M. J. (2010). Geometry controls conformation of graphene sheets: Membranes, ribbons, and scrolls. ACS Nano, 4(7), 3869-3876.

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Published

2015-11-15

How to Cite

Alhumade, H., Nauman, H., Elkamel, E., Yu, A., & Elkamel, A. (2015). CORROSION PROTECTION OF STAINLESS STEEL TYPE 304 USING GRAPHENE COMPOSITES. MATTER: International Journal of Science and Technology, 1(2), 57–72. https://doi.org/10.20319/mijst.2015.12.5772